Unusual Luminescence Properties of Heterometallic REE Terephthalates

The influence of auxiliary rare-earth element (REE) ions (M3+, M = Y, Gd, Tb) on the luminescence properties of the (EuxM1–x)2(BDC)3(H2O)4 (BDC2– = 1,4-benzenedicarboxylate) series was studied. The overall quantum yields (QYs) of the EuxM1–x series (M = Y, Gd; x > 0.05) appeared to be independent of both the ratio and the type of auxiliary metal ion. It is shown that M = Tb3+ does not cause luminescence enhancement.

Link: http://onlinelibrary.wiley.com/doi/10.1002/ejic.201403071/abstract

Authors: Grishko Aleksei Y., Utochnikova Valentina V., Averin Aleksei A., Mironov Andrei V.,

Kuzmina Natalia P.

Magazine: European Journal of Inorganic Chemistry

Publication year: 2015

 

 

Unusual Luminescence Properties of Heterometallic REE Terephthalates